两亲性环状共聚物的设计及性能探索分析研究 功能材料学专业VIP免费

目录摘要·················································································1Abstract·············································································2第1章前言·······································································4第1.1节研究背景··························································41.1.1环状聚合物························································41.1.2环状接枝聚合物··················································41.1.3刺激响应型聚合物···············································5第1.2节研究目的与意义·················································5第2章实验部分·································································6第2.1节实验原料··························································6第2.2节聚合物的合成····················································62.2.1线型聚合物l-PHD的合成······································62.2.2环状聚合物c-PHD的合成······································72.2.3环状接枝聚合物(c-PHD)-g-PCL的合成·····················8第2.3节环状接枝聚合物的自组装及刺激响应性探索·············9第2.4节表征方法··························································9第3章结果与讨论····························································10第3.1节4-硫代苯甲酰硫-4-氰基戊酸3-(2-醛基-3-甲基苯氧基)丙酯（FBCP）的表征···························································10第3.2节聚合物的合成与表征··········································103.2.1l-PHD的合成与表征···········································103.2.2c-PHD的合成与表征···········································123.2.3(c-PHD)-g-PCL的合成与表征································13第3.3节聚合物水溶液温敏性能的研究······························143.3.1聚合物浓度的影响··············································143.3.2NaCl盐浓度的影响·············································163.3.3pH和CO2鼓泡的影响··········································16第3.4节环状接枝聚合物的性能探索·································173.4.1环状接枝聚合物溶液温敏性能的研究······...