锂离子电池安全手册LIBSafetyHandbookDec.2005目录第一章绪论..................................................................................................................4第一节锂离子电池的诞生与发展.......................................................................41.1金属锂电池的诞生与发展........................................................................41.2锂离子电池的诞生与发展........................................................................51.3锂离子电池的工作原理............................................................................61.4锂离子电池的分类....................................................................................6第二节锂离子电池的材料...................................................................................72.1锂离子电池正极材料................................................................................72.2.1层状LiCoO2.....................................................................................82.2.3层状LiNiO2.....................................................................................92.2.4层状LiNi1-x-yCoxMnyO2....................................................................92.2.5尖晶石型LiMn2O4.........................................................................102.2.6磷酸盐............................................................................................112.2负极材料..................................................................................................142.2.1天然石墨........................................................................................142.2.2人造石墨........................................................................................162.2.3中间相沥青炭微球(MCMB).........................................................162.2.4硬炭材料........................................................................................172.2.5合金与合金类氧化物负极材料....................................................172.2.6Li4Ti5O12.........................................................................................182.3电解液......................................................................................................182.3.1液体电解液....................................................................................192.3.2聚合物电解质................................................................................25第三节锂离子电池的安全性...........................................................................283.1安全测试标准..........................................................................................283.2锂离子电池的反应..................................................................................293.3.1锂离子电池内的热反应................................................................293.2.2电极材料安全性的判断标准........................................................313.4改善电池安全性的措施..........................................................................32第二章安全测试原理................................................................................................33第一节短路（Shortcircuit）.............................................................................331.1测试过程Testprocedure.........................................................................331.2短路Short-circuitmechanism..........
