精品文档---下载后可任意编辑摘要:介绍了新型碳材料在染料敏化太阳电池(DSSCs)中应用的讨论进展,在 TiO2光电极中加入多层碳纳米管(MWCNTs)不仅能增加电子寿命,提高电池转换效率,还能减少电极裂纹,增加电极的机械强度;用碳纳米粉或碳纳米管替代 Pt 作为对电极能降低电池制作成本,提高电极的电化学活性,提高电池转换效率,与其他材料复合还能增加电池机械性能和环境的稳定性。综述了材料的制备工艺和 MWCNTs 加入比例对电池性能的影响及单层碳纳米管(SWCNT)和 Ag 复合作为对电极的性能。总之,新型碳材料由于其诸多的优点是应用在 DSSCs 中理想的电极材料。关键词:染料敏化太阳电池;碳纳米管;TiO2;电荷转移电阻Abstract:The application of new carbon materials in dye-sensitized solar cells was introduced. The electron lifetimeand cell conversion efficiency could be improved significantly by adding MWCNTs in the TiO2 electrode. Thisprocess could also reduce the electrode crack and enhance the mechanical strength of electrode. The use of carbonnanoparticles and CNTs as the counter electrodes to replace Pt could reduce the cost of cells, and enhance theelectrochemical activity of electrode and the cell conversion efficiency. The composite film of new carbon materialsand the other material could improve the mechanical property and the environment stability. The influence ofpreparation technology of materials, the MWCNTs percentage on the cell performance and the performance ofelectrode composed of single wall carbon nanotube(SWCNT) and Ag were also be discussed. In a word, the newcarbon materials are perfect electrode material applied in DSSCs.Key words: DSSC; CNT; TiO2; charge transfer resistance引言:1991 年,Gratzel 等人[1]报道了基于染料敏化纳米晶多孔 TiO2薄膜太阳电池的光电转化效率可达到 7.1%,引起了世界各国科学家的极大兴趣与关注 由于 DSSC 具有成本低廉,理论转化效率高,制备工艺简单,对环境友好等优点,成为了新一代太阳电池的讨论热点与重点。目前,其...