1 2 饱和脂肪烃 1．完成下列反应式： 答案： (1) (2) (3) (4) 3 不饱和脂肪烃 一．完成下列反应： (3) + Br H (4) + C l 2 hv C H 3 C H 2 C H 3 B r 2 (1) + hv C H 3 C C H 3 C H 3 C l 2 C H 3 hv (2) + CH3CH2CH3 +Br2CH3CHBrCH3hvCH3CCH3CH3CH3CH3CCH3CH2ClCH3Cl2+hvBr+HBrClCl+Cl2hvCH3HI+Cl3CCHCH2CH3CH2CHCH2HOClCH3CCCH3HCCCH2CHCH2HBr++H2+Pd/BaSO4+HBr( 3 )( 4 )( 5 )( 6 )( 7 )OOO+( 8 )H 2 S O 4 C H 3 C H 2 C C H 2 C H 3 + C H 3 C H 2 C C H 2 C H 3 HCl H 2 O + (1) (2) 2 答：反应产物为： 二、完成下列反应式 1．(1)(2)CH2H2OH2SO4C(CH3)2 2．H2O2CH3HBr 3．O3Zn/H 2OCH 3CH 2CH=CH 2 4．(1)(2)CH2H2OH2SO4 5．℃Br2300 6．H2OCl2＋＋ 7．(1)(2)CH2H2O2CH2CHOHB2H6 8．KMnO4OH 9．H+KMnO 4C2H5C2H5CH=CH 10．H3O+C6H5CO3H 11．H+KMnO 4C2H5 CH3CH2CCH3ClCH3（1） （2） CH3CH2CCH3OSO3HCH3CH3CH2CCH3OHCH3（3） ICH3（4） Cl3CCH2CH2Br（5） CH3CH2CH CH2ClOH（6） CH3CH=CHCH 3（7） HC CCH2CH CH3Br（8） OOO 3 12．H2O2＋OsO4 13．CH2H2O2OH＋B2H6 14．H2O2OH＋CH3B2H6 15．(1)(2)O3(CH 3)2CHZn/H 2OCH 3CH 16．H2O＋＋Br2 17．NBS＋CH3 18．CH2H2OCl2C(CH3)2＋ 19．＋CH3Br2CCl4 20．(1)(2)O3Zn/H2OCH3 21．KMnO4OHHC2H5CC2H5HC 22．H2O2＋CH3B2H6OH 23．Br2＋CCl4 24．H2OCH3＋CH3OsO4NaHSO3 25．CH2CHHBrC6H5ROOR 26．(1)(2)O3CH2Zn/H 2OC2H5CCH3 27．HIF3C＋CH=CH2 28．CH2CH2 H2O2 OHB2H6 29．CH2H+I＋ClC(CH3)2 4 30．H2SO4H3O+CH3 ＋ 答案： 1. OHCH3C(CH3)2 2. BrCH3 3. CH3CH2CHO + HCHO 4. OHCH3 5. Br 6. HOCl or ClOH 7. CH2CH2CH2OH 8. OHOH 9. COOH2CH 2CH3 10．(± )OHOHO； 11. COOHCOCH3(CH2)3 12. OHOH 13. CH2OH 14. CH3OH 15. (CH 3)2CHCHOCH3＋CHO 16. BrOH 17. BrCH3 18. CH2ClC(CH3)2OH 19. BrCH3Br (± ) 20. CHOCOCH3(CH2)3 21. OHHHOC2H5HC2H5(± ) 22. CH3OH or CH3OH 23. BrBr(± ) 24. CH3CH3OHOH 25. CH2CH2C6H5OH 26. HC2H5C＋COCH3HO 27. CH 2 CH 2 IF3C 28. CH2CH2HOOH 29. CH 2(CH 3)2CHICl 30. OSO3HCH3OH； CH3 三、...
