Section1.ChemicalProductandCompanyIdentificationProductsNameLithiumIonBatteryP322033,P682052,P462539,P543638,P552025,P682634-R01,P7234048,P752631-2S-R01DescriptionLithiumCobaltDioxideChemistryManufactureNameAddressPostcodeEmergencyTelephoneNo.FaxE-mailMSDSCodeDatePrepared2014-1-2Section2.Composition/InformationonIngredientsChemicalNamePercentofContentCASNo.OSHA(PEL)ACGIH(TLV)LithiumCobaltDioxide(LiCoO2)≤35%12190-79-3N/A0.02mg/m3asCoGraphite(C)25%~30%7782-42-515mg/m3(asdust)3.5mg/m3PolyVnylidene<20%24937-79-9N/AN/AFluoride(PVDF)AcetyleneBlack0.5%~3%1333-86-4N/AN/AElectrolyte5%~15%623-53-0/21324-40-3N/AN/AACGIH:AmericanCouncilofGovernmentIndustrialHygienistsTLV:ThresholdLimitValuearepersonalexposurelimitsdeterminedbytheACGIHSection3.HazardsSummarizingDangersortN/ARoutesofentry1.EyesandSkin–Whenleaking,theelectrolytesolutioncontainedinthebatteryirritatestooculartissuesandtheskin.2.Inhalation-Respiratory(andeye)irritationmayoccuriffumesarereleaseddueheatoranabundanceofleakingbatteries.3.Ingestion–Theingestionofthebatterycanbeharmful.Contentofopenbatterycancauseseriouschemicalburnsofmouth,esophagusandgastrointestinaltract.HealthharmExposuretoleakingelectrolytefromrupturedorleakingbatterycancause:1.Inhalation-Burnsandirritationoftherespiratorysystem,coughing,wheezing,andshortnessofbreath.2.Eyes-Redness,tearing,burns.Theelectrolyteiscorrosivetoalloculartissues.3.Skin-Theelectrolyteiscorrosiveandcausesskinirritationandburns.4.Ingestion-Theelectrolytesolutioncausestissuedamagetothroatandgastrointestinaltrack.EnvironmentharmNotnecessaryunderconditionsofnormaluseExplosiondangerThebatterymaybeexplosiveathightemperature(above60℃)orexposingtothefire.Section4.FirstAidMeasuresSkincontactNotanticipated.Ifthebatteryisleakingandthecontainedmaterialcontactstheskin,flushwithcopiousamountsofclearwaterforatleast15minutes.EyecontactNotanticipated.Ifthebatteryisleakingandthecontainedmaterialcontactseyes,flushwithcopiousamountsofclearwaterforatleast15minutes.Getmedicalattentionatonce.InhalationNotanticipated.Ifthebatteryisleaking,removetofreshair.Ifirritationpersists,consultaphysician.IngestionNotanticipated.Ifthebatteryisleakingandthecontainedmaterialisingested,rinsemouthandsurroundingareawithclearwateratonce.Consultaphysicianimmediatelyfortreatment.Section5.FireFightingMeasuresUnusualFireandExplosionHazardsBatterymayexplodeorleakpotentiallyhazardousvaporssubjectto:exposedtoexcessiveheat(abovethemaximumratedtemperatureasspecifiedbythemanufacturer)orfire,over-charged,shortcircuit,puncturedandcrushed.HazardousCombustionProductsFire,excessiveheat,orovervoltageconditionsmayproducehazardousdecompositionproducts.Damagedbatteriescanresultinrapidheatingandthereleaseofflammablevapors.ExtinguishingMediaDrychemicaltypeextinguishersarethemosteffectivemeanstoextinguishabatteryfire.ACO2extinguisherwillalsoworkeffectively.FireFightingProceduresUseapositivepressureself-containedbreathingapparatusifbatteriesareinvolvedinafire.Fullprotectiveclothingisnecessary.Duringwaterapplication,cautionisadvisedasburningpiecesofflammableparticlesmaybeejectedfromthefire.Section6.AccidentalReleaseMeasuresThematerialcontainedwithinthebatterywouldonlybereleasedunderabusiveconditions.Intheeventofbatteryruptureandleakage,collectallthereleasedmaterialsthatarenothotorburninginanappropriatewastedisposalcontainerwhilewearing...