有机合成竞赛习题VIP免费

有机合成习题1. 合成M eOOMeMeOM eOOCCOOMeTMMeOOMeMeO+MeOOCCCCOOMeOMeOMeOOMePh 3P+CH 2OMeXOM eOHOMeOMeCHO+CH 3 CHOOM eOM eOHOM eOHOMeAOMeOMeOMeOMeOHCBCOMeOMeO( I )OHOMeOMeCH 2 BrOMePPh 3( II )( I )( II )+MeOOMeMeOMeOOCCCCOOMeMeOOMeMeOMeOOCCOOMeMeOOMeMeOMeOOCCOOMeA'B'C'Y答案：A: CH 3I, OH -B : CO, HCl, ZnCl2C: CH 3CHO, OH-A’: CH 3I, OH -B ’: HCHO, HBr, ZnCl2C’: PPh 3, LDA Y: DDQ 2. 写出字母代表的化合物的结构：FClCl1. AcCl , AlCl32. NaOClASOCl 2BCH2(COOEt) 2Mg(OEt) 2C1. TsOH , 2. EtOH , H+FClClOEtOOHC(OEt) 3Ac 2ODNH2ENaHNaOHFClNCOOHONHNHDMSOTM答案：ABCDETMFClClCOOHFClClCOClFClClOCOOEtCOOEtFClClOCOOEtOEtFClClOCOOEtNHFNNCOOHONH3. 写出字母代表的化合物的结构：OCH 3O1. HOCH2CH 2OH , H+2. Ph 3 P=CHCH3CH3OOCH31. OsO42. TsClAOH-BH3 O+C(C 13H 18O 2)Et 3N225 oCCH-CH 3OCH 3OD1. Ph 3CLi2. CH 3IE1. HSCH2CH 2 SH2. LiAlH43. Hg2+ , H 2 OFN 2H4OH- , 1. Cr(VI)2. CH 3Li3. H+CH 2CH 3CH 3CH 3答案：CH 3OOTsOOHCH 3ACH3CH 3OOOBCH 3OCH3OCDEFOCH 3CH 3O-OCH 3CH 3CH 3OOHCH 3CH 3CH 3O4. 写出字母代表的化合物的结构：OOCH3EtONaOABC (C 15H 21O4N)NHHOOCH+H2 OH2 O回流CH 3OHOO答案：CABOOCH3CH 3OOOCH3CH 2-N+COOHCH 3OHN+OCOOH5. 写出字母代表的化合物的结构：BrBrNaCN1. HNO 32. SOCl 2ABBase.CH 3O+DE(C 16H 12O2) 七种氢答案：ACNCNBOOClClCCNCNOODCOOHCOOHOODOO6. 写出字母代表的化合物的结构：OHCC-Na+NH 3(l)OHCCHHg2+ , H 2OOHCH 3OOMeClOAlCl 3A(C 10H 10O 2)t-BuONaB (C 18H20O 2)答案：ABOMeOOOMe7. 写出字母代表的化合物的结构：CH 3ClCl2PCl 5ABC(C 22H17N 2Cl)AlCl 32C 6H6NHN答案：CBACCl 3ClCClPh 2ClPh 2CClNN8. 写出字母代表的化合物的结构：A (C 12H20O 6)CH3OEtOBrCH 2(COOEt)2EtONaCNEtONaB (C 15H23NO 6)C(C 17H 28O 8)EtONaD(C 15H 22O7)1. H 2 O , OH- , 2. H 3O+ , E (C 7H 10 O3)1. NaBH42. H 3O+FEtONaGOHH2OI(C 9H 14O 3)EtOHH+答案：DEFABCGHIEtOOCCOOEtCOOEtCH 3EtOOCCOOEtCH3COOEtCNEtOOCCOOEtCH 3COOEtCOOEtCOOEtCH 3OCOOEtCOOEtCH3OCOOHOC-C...