有机化学试题库三——完成反应式题及解答

1 试题库三——完成反应式题及解答 1． 2． 3．CH3CH2CH=CH2 → CH3CH2CH2CH2OH 4．CH3CH=CH2 5．(CH3)2C=CHCH2CH3 6．CH2=CHCH2OH → 7．CH3CH2CH2C≡CH + HCl（过量）→ 8．CH3CH2C≡CH + HBr（过量）→ 9．CH3CH2C≡CCH3 + KMnO4 10．CH3CH2C≡CCH3 + H2O 11．CH2=CHCH= CH2 + CH2=CHCHO → 12． 13． 14． 15． 16． 17． 18． 19． 20． (CH 3)2C=CHCH 3HBr①②O3Zn粉, H2OClCH2CHCH2OHOH△H+H2SO4HgSO4CH3+ HBr+ Cl2高温+ Cl2CH 2CH 3Br2+CH(CH 3)2Cl2+高温CH3① O3② H2O △CH3 ①② H2O △H2SO4B2H6①② H2O2① O3② H2O △CH=CH2CH3CH=CH2KMnO4CH3OCH=CH 2+ HBr 2 21． 22． 23． 24． 25． 26． 27． 28． 29． 30． 31． 32． 33． 34． 35． 36．CH2=CHCH2Cl CH2=CHCH2CN 37． (CH3)3CCl + NaOH 38． (CH3)2CHCH2CH2OH + HBr 39． 40． 41． + CH2Cl2AlCl3+CH 3HNO 3+ KMnO4H+△+CH=CH 2Cl 2C6H5CH2Cl MgCO2H+H2OCH 2=CHCH 2Br +NaOC 2H5CH=CHBrCH2BrAgNO 3室温乙醇++ Br2KOH-乙醇△CH2=CHCHOCH2ClClH2ONaOH, △H2OClCH 3OH-+SN2历程H2OCH3OH-+ClSN1历程Br KOH-乙醇H2OOH + HCl 无水ZnCl2+ HIOCH 3CH2CH2OCH 3（过量）FeBr2SO3HOHAlCl3CH3H2SO4SO3/CH3BrEtONa 3 42． 43．(CH3)2CHBr + NaOC2H5 44． 45． CH3COOH + CH3CH2CHO 46． CH3COCH2CH2CH2CHO 47． 48． 49．CH3COCH2CH3 + H2N-OH → 50． Cl3CCHO + H2O → 51． 52．CH3CH2CHO 53．C6H5COCH3 + C6H5MgBr → 54． 55． 56．(CH3)3CCHO 57． 58． 59． 60． 61． 62．CH2=CHCH2CH2COCH3 + HCl → 63．C6H5CHO + CH3COCH3 → 64． 65． 66． + HIOCH3（过量）CH 3CH 2CH 2CH 2CHCH 3OHKMnO4OH-HIO4HIO4CH3OH+ Br2CH 3CH 2CH 2CHCH 2CH 3OH浓 H2SO4△（分子内脱水）CHOH3C+KMnO4稀 NaOHH2OH++OH2NNHC 6H5NaOH浓O + (CH3)2C(CH 2OH) 2无水HCl+ONa2CrO7△H+KMnO4CHO室温CCH 3OCl2 H2OOH-,CCH 3OCl 2+H+H2OH+CH3COCHCO 2C2H5CH3OH-,稀△①② ,CH3COCHCO 2CH3CH2CO2CH3△浓 NaOHCH3CH2CHCOOHOH△+OH2NOH 4 67． 68． 69． 70． 71． 72． 73． 74． 75． 76． 77． 78． 79． 80．HOCH2CH2COOH 81．NCCH2CH2CN + H2O 82． 83．CH3COCl + 84． 85．CH3CH2COO C...