《化学反应与能量》单元考试参考答案(每小题3分,共48分)17、(12分)1⑴:4CH⑵4(g)+2O2(g)=CO2(g)+2H2O(l)△H=-891.5kJ/mol33.33%b⑶①②5a/4(每空3分)18、(5分)H2(g)+1/2O2(g)==H2O(g)ΔH=–241.8kJ·mol-1(3分)–285.8(2分)19、(6分)2N2H4(g)+2NO2(g)=3N2(g)+4H2O(g)ΔH=–1135.7kJ·mol-1(3分)N2H4(g)+2F2(g)=N2(g)+4HF(g)ΔH=–1126kJ·mol-1(3分)20、(9分)(1)N2(g)+2O2(g)=2NO2(g)ΔH=+67.8kJ·mol-1(3分)(2)C2H2(g)+O2(g)=2CO2(g)+H2O(l)ΔH=–1300kJ·mol-1(3分)(3)N2(g)+H2(g)=NH3(g)ΔH=-46kJ·mol-1(3分)21、(7分)C(金刚石、s)=C(石墨、s)△H=-1.90kJ/mol(3分)石墨(1分)(3分)22、(7分)解:设1tCaCO3分解生成生石灰理论上需要吸收的热量为xCaCO3(s)=CaO(s)+CO2(g)∆H=175.7kJ/mol100kg175.7kJ1000kgxx==1757kJ(3分)题号12345678答案ABDBCACADD题号910111213141516答案DDBDDBCAC设需要含杂质10%的焦炭质量为yC(s)+O2(g)=CO2(g)∆H=-393.5kJ/mol,12kg393.5kJy90%1757kJy=kg(4分)答:1tCaCO3分解生成生石灰理论上需要含杂质10%的焦炭59.53千克。23、(6分)解:①6+②得总反应热为零的总反应方程式③7CH4(g)+3O2(g)+H2O(g)=7CO(g)+15H2(g)∆H3=0kJ/mol(3分)依据总反应方程式③可知V(O2):V(H2O)=3:1而O2的体积占空气体积的21%,所以V(空气):V(H2O)=100:7。(3分)