作业10章-Microsoft-Word-文档VIP免费

第十章醇和酚作业参考答案1、推测下列反应的机理（1）OHCH=CH2CH3OHBrOHCH=CH2H+OHCHCH3+OHCH3+CH3OH+（3）H+OOHH+OH++OHOH+OHH+O（4）OHH++++H+OHOH2H2O++H++H+H+2、如何完成下列转变？（1）CH3O(CH3)3C(CH3)3CH2OO(CH3)3CCH3(CH3)3CCH3MgIEt2OOHCH3(CH3)3CH2SO4（2）BrCH2BrHBrOBrH2OEt2OMgMgBrHCHCH2OHCH2Br（3）OHOHCH2OHOHOHOCH2OHHIO4NaBH4（4）OHC6H5OHOHC6H5H2SO4OHOHC6H5C6H5KMnO4OHOHC6H53、A的结构：OBr4、推测下列化合物的结构OH(CH3)3C(1)(2)(3)OHCH3CH2CH2OHCH2CCH3CH3(4)OHBrCHCH2CH3(5)CH3CH3CCH2CH2CCH3OHOHCH3OHBrOH(6)(7)(8)(C6H5)3COHHO问题10。3（1）将下列化合物命名：（1）5—甲基—1—己醇（2）三苯甲醇（3）2，4—二甲基—1—戊醇（4）4—苯基—1，6—庚二烯—4—醇（2）写出下列化合物的构造或构型(1)(2)(3)CH3CH2CHCHCH3CH3OHOHCH3CHCH2C=CHHCH2CH3(4)CH3OHCH3CCH2CH3问题10。4下列化合物应如何合成？(1)C6H5CHOCH3CH2MgBr+Et2OH2OC6H5CHCH2CH3OH(2)C6H5MgBr+OHCH3CCH3OEt2OH2OC6H5C(CH3)2(3)CH3CH3CH2MgBr+OHEt2OH2OCH3COOC2H5CH3CH2CCH2CH3(4)CH3CH2CH2CH2CH2MgBr+CH3COOC2H5Et2OH2OCH3OHCH3(CH2)4C(CH2)4CH3(5)CH3CH2CHOCH3)2CHCH2MgBr+OHCH3CH2CCH2CH(CH3)2(Et2OH2OO(6)C6H5)3CMgBr+(HCHEt2OH2O(C6H5)3CCH2OHCH3CH2CCH3(7)O+HCCNaEt2OH2OCH3CH2CCCHCH3OH(8)CH3CH2MgBrC6H5CCH3O+Et2OH2OCH3OHC6H5CCH2CH3问题10。5如何由下列原料合成1—苯乙醇（C6H5CH（OH）CH3）？OH(1)C6H5BrC6H5MgBrEt2OMgCH3CHOC6H5CHCH3C6H5CHO(2)H2OCH3MgBrEt2OOHC6H5CHCH3(3)H2OOHC6H5CHCH3C6H5CCH3ONaBH4(4)C6H5CH=CH2H2OH2SO4OHC6H5CHCH3问题10。6如何由下列原料合成2—苯乙醇（C6H5CH2CH2OH）？(1)C6H5BrMgC6H5MgBrEt2OH2OC6H5CH2CH2OHO(2)C6H5CH=CH2C6H5CH2CH2OHB2H6THFH2O2OH(3)C6H5CCHLindlarPdH2C6H5CH=CH2C6H5CH2CH2OHB2H6THFH2O2OHC6H5CH3COOC2H5(4)Et2OH2OLiAlH4C6H5CH2CH2OH问题10。8写出下列化合物用高碘酸氧化生成的产物。CH3OH(1)OHCH3OOHIO4(2)CH3OHOHHIO4OCHO(3)OOHHIO4CH2OH(4)OHOHHIO4OO问题10。10写出下列反应的产物。CH3(1)CH3(2)CH2OHOHBrCH3(CH3)3CBrO(3)(4)OHCH3CCH2CH3OHCHOOCH3NO2