附录Ⅶ物质的摩尔热容(100kPa)(1)单质与无机物物质Cp,m(298.15K)Cp,m=a+bT+cT2,或Cp,m=a+bT+c′T-2ab×103c×106c′×10-5适用温度J·K-1·mol-1J·K-1·mol-1J·mol-1·K-2J·mol-1·K-3J·K·mol-1范围/KAg(s)25.4823.975.284-0.25293～1234Ag2O(s)Al(s)65.5724.3520.6712.38273～931.7Al2O3-α79.092.3837.535-26.86127～1937Al2(SO4)3(s)Br2(g)259.4368.5761.92-113.47298～110035.9937.200.690-1.188300～1500第1页Br2(l)C(金刚石)35.66.079.1213.22-6.19298～1200C(石墨)8.6617.154.27-8.79298～2300CO(g)29.14227.65.0290～2500CO2(g)37.12044.149.04-8.54298～2500Ca(s)26.2721.9214.64273～673CaC2(s)62.3468.611.88-8.66298～720CaCO3(方解石)CaCl2(s)81.83104.5221.92298～-25.94120072.6371.8812.72-2.51298～1055CaO(s)48.5343.834.52第2页-6.52298～1800Ca(OH)2(s)CaSO4(硬石膏)Cl2(g)33.936.691.05-2.523273～-6.5611373273～1500Cu(s)24.4724.564.18-1.201273～1357CuO(s)44.438.7920.08298～1250Cu2O-α69.862.3423.8584.597.6577.4991.92298～1200F2(g)31.4634.691.84-3.35273～200Fe-α25.2317.2826.69273～1041FeCO3(s)82.1348.66112.1第3页298～885FeO(s)51.152.806.242-3.188273～1173Fe2O3(s)104.697.7417.13-12.887298～1100298～-41.881100300～1500Fe3O4(s)143.4278.91H(g)20.80H2(g)28.8329.08-0.842.00D2(g)29.2028.5770.8791.958298～1500HBr(g)29.1226.155.861.09298～1600HCl(g)29.1226.534.601.90298～2000Hl(g)29.1226.325.940.92298～1000第4页H2O(g)33.57130.1211.30273～2000H2O(l)H2O2(l)H2S(g)75.29682.2933.9729.2915.69273～1300H2SO4(l)l2(g)137.5755.9740.1249.79298～386.8I2(g)N2(g)36.8729.1226.874.27273～2500NH3(g)35.6529.7925.48-1.665273～1400NO(g)29.86129.583.85-0.59273～1500NO2(g)N2O(g)37.9038.7042.9345.698.548.62第5页-6.74-8.54273~500N2O4(g)279.0108.021.9329.3783.8931.4630.753.3914.90-3.77O5(Ng)O(g)O2(g)273～2000O3(g)S(单斜)38.1523.6414.9029.08368.6～392S(斜方)22.6014.9826.11273～368.6(g)32.5536.111.09273～2000S(g)SO2(g)39.7947.70-3.517.171-8.54298～1800SO3(g)50.7057.3226.86-13.05273～900第6页(2).有机化合物在指定温度范围内恒压热容可用下式计算：Cp,m=a+bT+cT2+dT3Cp,m(298.15K)物质J·K-1·molJ·K-1·-1Cp,m=(T)ab×103c×106d×106适用温度J·mol-1J·mol-1J·K·m范围/K·K-2烃类298～·K-3ol-1mol-1CH4(g),甲烷35.71517.45160.461.117-7.2051500298～C2H2(g),乙炔43.92823.46085.768-58.34215.8701500298～C2H4(g),乙烯43.564.197154.590-81.09016.8151500298～C2H6(g),乙烷52.6504.936182.259-74.85610.7991500298～C3H6(g),丙烯63.893.305235.860-117.60022.6771500第7页298～C3H6(g),丙烷73.51-4.799307.311-160.15932.7481500298～79.54-2.958340.084-223.68956.530150298～85.652.540344.929441.6641500298～78.918.774342.448-197.32234.2711500298～87.828.381307.541-148.25627.2841500298～89.127.084321.632-166.07133.4971500298～97.450.469385.376-198.88239.9961500298～96.82-6.841409.643-220.54745.7391500298～C6H6(g),苯81.67-33.899471.872-298.34470.8351500第8页C4H6(g),1,3-丁二烯C4H8(g),1-丁烯C4H8(g),顺-2-丁烯C4H8(g),反-2-丁烯C4H8(g),2-甲基两烯C4H10(g),正丁烷C4H10(g),异丁烷C6H6(l)苯135.7759.50255.01281～353298～C6H12(g),环己烷C6H14(g),正己烷C6H14(l)正己烷C6H5CH3(g),甲苯C6H5CH3(l),甲苯C6H4(CH2）(g),邻二甲苯C6H4CH3）2106.27-67.664679.452-380.76178.0061500298～143.093.084565.786-300.36962.0611500194.93298～103.76-33.882557.045-342.37379.8731500281～382298～133.26-14.811591.136-339.59074.6971500157.1159.62326.98187.9187.9(l),邻二甲苯298～127.57-27.384620.870-363.89581.3791500第9页C6H4(CH3）2(g),间二甲苯C6H（CH3）2（l),间二甲苯C6H4(CH3）2183.3183.3298～126.86-25.92460.670-350.56176.8771500(g),对二甲苯C6H4（CH3）2183.7183.7(l),对二甲苯35.36291～54.4醛35.3618.82058.379-15.6061500300～700含氧化合物HCOH(g),甲HCOOH(g),99.04甲酸HCOOH(l),49.4甲酸CH3OH(g),甲醇CH3OH甲醇CH2COH(g),123.4(l),62.830.6789.20-34.53981.620.42103.68-24.640300～70031.054121.457-36.577第10页298～乙醛CH3COOH(l),乙酸CH3COOH(g),乙酸C2H5OH(l),乙醇C2HOH(g),乙醇CH3COCH3（l),丙酮CH3COCH3(g),两酮C2H5OC2H5(l),乙醚CH3COOC2H5(l),乙酸乙酯第11页169.0150072.454.81230114.621.76193.09-76.78300～700283～348300～1500298～320298～150071.1106.52165.7575.3124.7320.694-205.38-99.80975.3124.7355.61232.222.472201.78-63.521170.7290293C6H5COOH（s),苯甲酸155.2155.2卤代烃CH3Cl(g),氯甲烷CH2Cl2(g),二氯甲烷CHCl3（l),氯仿CHCl3(g),氯仿CCl4(l),四氯化碳CCl4(g),甲氯化碳C6H5Cl(l),氯苯含氮化合物第12页273～800273～330273～800273～80040.7914.90396.2-31.55251.3833.4765.3116.365.8129.506148.942-90.713131.7597.99111.7185.51145.6NH（CH3）269.37(g),二甲胺C5H5N(l),吡啶C6H5NH2(l),苯胺C6H5NO2(l),硝基苯140.2293199.6338.28-1068.62022.1278～348185.4293第13页
