常见溶剂及高聚物的溶度参数

沸点（℃） V(cm3.mol-1)δ(cal1/2.cm-3/2)P溶剂二异丙醚正戊烷异戊烷正己烷正庚烷乙醚正辛烷环己烷甲基丙烯酸丁酯氯乙烷1,1,1-三氯乙烷乙酸戊酯乙酸丁酯四氯化碳正丙苯苯乙烯甲基丙烯酸甲酯乙酸乙烯酯对二甲苯二乙基酮间二甲苯乙苯68.514136.111627.91176913298.414734.5105125.716480.710916010612.37374.1100149.3148126.513276.597157.5140143.811510210672.992138.4124101.7105139.1123136.212377.0507.0507.307.4507.40.0337.5508.208.20.0968.50.3198.50.0698.50.078.550.1678.608.6508.6608.70.1498.70.0528.7508.80.2868.80.0018.80.001异丙苯甲苯丙烯酸甲酯邻二甲苯乙酸乙酯1,1-二氯乙烷甲基丙烯腈苯三氯甲烷丁酮四氯乙烯甲酸乙酯氯苯苯甲酸乙酯二氯甲烷顺式-二氯乙烷1,2-二氯乙烷乙醛萘环己酮四氢呋喃二硫化碳二氧六环溴苯152.4140110.610780.390144.412177.19957.38590.383.580.18961.78179.689.5121.110154.580125.9107212.714339.76560.375.583.57920.857218123155.810964-658146.261.5101.3871561058.860.0028.90.0018.90.00190.0019.10.1679.10.2159.10.7469.1509.30.0179.30.519.40.019.40.1319.50.0589.70.0579.70.129.70.1659.80.0439.80.7159.909.90.389.90100100.029100.029丙酮硝基苯四氯乙烷丙烯腈丙睛吡啶苯胺二甲基乙酰胺硝基乙烷环己醇正丁醇异丁醇正丙醇乙腈二甲基甲酰胺乙酸硝基甲烷乙醇二甲基亚砜甲酸苯酚甲醇碳酸乙烯酯二甲基砜56.174210.81039310177.466.597.471115.381184.19116592.516.576161.1104117.391107.89197.47681.15315377117.957-125478.357.618971100.737.9181.887.565412486623875100.695100.62510.40.09210.450.80210.70.75310.70.17410.80.06311.10.68211.10.7111.40.07511.40.09611.40.11111.90.15211.90.85212.10.77212.60.29612.60.7812.70.26813.40.81313.514.50.05714.50.38814.50.92414.60.782丙二腈乙二醇丙三醇甲酰胺水218-219198290.1111（20）100635673401815.115.716.517.823.20.7980.4760.4680.880.819P52 常见溶剂的沸点、摩尔体积、溶度参数和极性分数（参考文献：高分子物理（第三版）复旦大学出版社）聚合物聚甲基丙烯酸甲酯δ9.0-9.5聚丙烯酸甲酯9.8-10.1聚乙酸乙烯酯聚乙烯聚苯乙烯聚异丁烯聚异戊二烯聚对苯二甲酸乙二酯聚己二酸己二胺9.47.9-8.18.7-9.17.7-8.07.9-8.310.713.6聚氨酯环氧树脂聚硫橡胶聚二甲基硅氧烷聚苯基甲基硅氧烷聚丁二烯聚四氟乙烯聚三氟氯乙烯聚氯乙烯聚偏氯乙烯聚氯丁二烯聚丙烯腈聚甲基丙烯腈109.7-10.99.0-9.47.3-7.698.1-8.66.27.29.5-10.012.28.2-9.412.7-15.410.7硝酸纤维素8.5-11.5P53 常见高聚物的溶度参数