※成分分析食品科学2016,Vol.37,No.02147不同产地绿茶饮料香气特征及差异分析刘盼盼1，刘晓辉2,*，罗龙新1，龙丹2，何群仙1（1.深圳市深宝实业股份有限公司，广东深圳518040；2.深圳市深宝华城科技有限公司，广东深圳518115）摘要：利用顶空固相微萃取与气相色谱-质谱联用法并结合相关性与气味活度值分析研究了不同产地绿茶饮料挥发性风味成分物质含量及构成差异。结果表明：低糖型绿茶饮料的香气总量要远高于无糖型，且不同产地绿茶饮料主要香气物质组成不同，主要共性成分是芳樟醇和柠檬烯；其中中国大陆饮料中含量较高的有酯类、酮类和烯类，日本饮料以醇类、烯类和醛类为主，中国台湾饮料中醇类、酯类的含量较高，而烯类含量很低。其中有10个香气组分与香气评分相关性较高，主要是反-氧化芳樟醇（0.93**）与花香呈显著正相关，顺-3-己烯醇（0.90*）和β-环柠檬醛（0.92**）与清香呈显著正相关，β-紫罗酮（－0.92**）与果香呈显著负相关，β-大马烯酮（0.95**）与甜香呈显著正相关，1-乙基吡咯（0.87*）与烘焙香呈显著正相关；6个气味活度值较高的组分分别是β-大马烯酮、β-紫罗酮、芳樟醇、大马酮、癸醛和柠檬烯，它们对整体香气贡献较大。关键词：绿茶饮料；挥发性成分；顶空固相微萃取；气味活度值ComparativeAnalysisofAromaCharacteristicsofGreenTeaBeveragesfromDifferentRegionsLIUPanpan1,LIUXiaohui2,*,LUOLongxin1,LONGDan2,HEQunxian1(1.ShenzhenShenbaoIndustrialCo.Ltd.,Shenzhen518040,China;2.ShenzhenShenbaoHuachengTech.Co.Ltd.,Shenzhen518115,China)Abstract:Headspacesolidphasemicroextraction(HS-SPME)combinedwithgaschromatography-massspectrometry(GC-MS)hasbeensuccessfullyappliedtoanalyzeandcomparevolatileflavorcompoundsofgreenteabeveragesfromdifferentregionsbythecombineduseofcorrelationanalysisandodoractivevalue(OAV).Theresultsshowedthatthetotalaromacontentoflow-sugargreenteabeverageweremuchgreaterthanthatoffree-sugarteabeverage.Althoughthemainaromacomponentsofgreenteabeveragesfromdifferentregionsweredifferent,commoningredients,includinglinaloolandlimonene,stillexisted;thecontentsofesters,ketonesandalkenesingreenteabeveragefrommainlandChinawerehigherwhilethecontentsofalcohols,alkenesandaldehydesingreenteabeveragefromJapanwerehigher;andthecontentsofestersandalcoholsingreenteabeveragefromTaiwan,Chinawerehigher,whilethecontentofalkenewasmuchlowerthanthatinmainlandChinaandJapan.Tenvolatilecompoundswerehighlycorrelatedwitharomaattributes,suchas(E)-linalooloxide(0.93**),whichwasfoundtobesignificantlyandpositivelycorrelatedwithfloralaroma,(Z)-3-hexenol(0.90*)andβ-cyclocitral(0.92**),whichwerefoundsignificantlypositivelycorrelatedwithgreenflavor,β-ionone(-0.92**),whichwasfoundtobesignificantlynegativelycorrelatedwithfruityaroma,β-damascenone(0.95**)wasfoundtobesignificantlyandpositivelycorrelatedwithsweetaroma,and1-ethylpyrrole,whichwasfoundtobesignificantlyandpositivelycorrelatedwithroast.Thereweresixmajorcomponentscontributingmostlytothewholearoma,includingβ-damascenone,β-ionone,linalool,damascone,decanalandlimonene.Keywords:greenteabeverage;volatilecomponents;headspacesolid-phasemicroextraction(HS-SPME);odoractivevalue(OAV)DOI:10.7506/spkx1002-6630-201602026中图分类号：TS272；O657.63文献标志码：A文章编号：1002-6630（2016）02-0147-06引文格式：刘盼盼,刘晓辉,罗龙新,等.不同产地绿茶饮料香气特征及差异分析[J].食品科学,2016,37(2):147-152.DOI:10.7506/spkx1002-6630-201602026.http://www.spkx.net.cnLIUPanpan,LIUXiaohui,LUOLongxin,etal.Comparativeanalysisofaromacharacteristicsofgreenteabeveragesfromdifferentregions[J].FoodScience,2016,37(2):147-152.(inChinesewithEnglishabs...
