1药学专业有机化学综合练习题参考答案一．命名下列化合物，若为立体结构式需标明构型。1.CH3CH2CHCH2CHCH3CH3CH32.(CH3)2CHCH2CHCHCH2CH3CH2CH3CH33.CH3CHCH2CHCH2CH2CH3CH3CH2CH32,4-二甲基己烷2,5-二甲基-4-乙基庚烷2-甲基-4-乙基庚烷4.CH3CHCH2CH2CHCH2CH3CH3CHCH3CH35.ClCH2CH36.BrCH3CH22,6-二甲基-3-乙基庚烷(1R,3R)-1-乙基-3-氯环己烷顺-1-乙基-4-溴环己烷7.H3CCH38.9.Cl10.Br3,6-二甲基二环[3.2.2]壬烷1,3,8-三甲基螺[4.5]癸烷5-氯螺[3.4]辛烷2-溴二环[4.3.0]壬烷11.CCCOOHCH3HCH3CH212.CH3CH2CH2CHCHCCCH3CH3CH2CH313.CH3CH=CHCCH14.CH=CH2CH3CCE-2-甲基-2-戊烯酸4-甲基-5-乙基-2-辛炔3-戊烯-1-炔1-戊烯-3-炔15.CHCH2CHCH3OHCH216.CCCH2HHH3CHCH3OH17.CH3CH2CH3OHH18.HSCH2CH2OH4-戊烯-2-醇(2R,4E)-4-己烯-2-醇(S)-2-丁醇2-巯基乙醇19.SO3HCH320.OHOH21.OH22.OHNO223.SO3HNO22-甲基苯磺酸间苯二酚2-萘酚5-硝基-2-萘酚5-硝基-2-萘磺酸24.CH3CH2OCH=CH225.CH3CHO26.CO2HOH27.CH3CH2CCH2CH(CH3)2O乙基乙烯基醚对甲基苯甲醛3-羟基苯甲酸5-甲基-3-己酮228.CH3CH2CHCH2COClCH329.HOHCO2HCH330.COOCH2CH33-甲基戊酰氯D-乳酸(R-2-羟基丙酸)苯甲酸乙酯31.CH3CH2CCH2COOCH3O32.HCON(CH3)233.CH3CH2CONHCH334.N(CH3)23-戊酮酸甲酯N,N-二甲基甲酰胺N-甲基丙酰胺N,N-二甲基苯胺35.NCOOH36.NNF.37.OCHO38.NCH339.COOHHH2NCH2SHβ-吡啶甲酸5-氟嘧啶2-呋喃甲醛3-甲基吡啶L-半光氨酸二．根据名称写出其结构式1.螺[3.4]辛烷2.2,7,7-三甲基二环[2.2.1]庚烷3.双环［3.2.1］辛烷4.2,3-二甲基-.2,4-己二烯CH3CCCH3CHCH3CHCH35.Z-3-甲基-2-氯-2-戊烯6.(Z)-3-乙基-2-己烯7.1,6-二甲基环己烯8.乙基9.乙烯基CCClCH3CH3CH2H3CCH3CCHCH2CH2CH2CH2CH3CH3CH3CH3CH2-CH2=CH10.异丁基11.异戊基12.苄基13.苯基14.烯丙基CH3CHCH2CH3CH3CHCH2CH2CH3CH2CH2=CHCH215.叔丁醇16.(2R,3R)-1,2,3-三氯丁烷17.(2R,3R)-,2,3-二氯-1-丁醇18.反-2-甲基-2-丁烯醇(CH3)3COHHClCH2ClCH3ClHClHCH2OHCH3ClHCCCH3CH2OHHH3C19.4,5-二甲基-2-乙基-1,3-己二醇20.甲异丙醚21.苯甲醚22.3-戊烯醛CH3CHCHCHCH3CH3CCH2OHOHCH2CH3HCH3OCH(CH3)2OCH3CH3CH2CHCH2CHO323.4-甲基-2-戊酮24.苯乙酮25.1-环己基-2-丁酮26.2-甲基-1-苯基-1-丁酮CH3CCH2CHCH3CH3OCOCH3CH2CCH2CH3OCCHCH2CH3OCH327.R-乳酸28.L-2-氨基丙酸29.丙二酸30.3-羟基戊二酸31.顺-丁烯二酸酐COOHOHHCH3H2NHCOOHCH3HOOCCH2COOHHOOCCH2CHCH2COOHOHOOO32.乙酸丙酸酐33.乙酸乙酯34.3-甲基丁酸乙酯35.N-甲基苯甲酰胺CH3COOCCH2CH3OCH3COOCH2CH3CH3CHCH2COCH2CH3OCH3CNHCH3O36.1,4-戊二胺37.N,N-二甲基苯胺38.N-甲基-N-乙基环己胺39.溴化甲基三乙基铵H2NCH2CH2CH2CHCH3NH2N(CH3)2NCH3CH2CH3NH3CC2H5C2H5C2H5Br-+40.氢氧化三甲基异丙基铵41.2-呋喃甲醛42.N-甲基-2-羟基咪唑43.5-乙基噻唑44.嘌呤NH3CCH3CH3CH(CH3)2OH-+OCHONNCH3OHNSC2H5NNNHN三．写出下列反应的主要产物1.CH3CHCH2+HBrCH3CHBrCH32.+HBrCH3CCH2CH3CH3CCH3CH3Br3.CH3+HICH3CH2CHCH3I4.CH3+HClCH3CH3CH2CCH3CH3Cl5+HBrCH3Br6.+HBrCH3Br7.CH2=CH－CH=CH2+CH2=CH－CHOCHO48.O+O9.(CH3)3CCH2CH3KMnO4,H+(CH3)3CCOOH10.CH3Cl2FeCl3CH3Cl11.C2H5+Cl2FeCl3C2H5Cl+C2H5Cl12.CH2CH3NBSCHCH3Br13.CH3NBSBrCH2BrBr14.+Br2FeBr3COOCOOBr+COOBr15.+Br2NO2CNFeBr3NO2CNBr16.(CH3)2CHCHCH3ClKOH/C2H5OH(CH3)2CCHCH317.BrKOH/乙醇CH3CH2CHCH3CH3CH=CHCH318.BrKOH/乙醇CH3CH2CCH3CH3CH3CH=CCH3CH319.CH3CH2CH2Br+NaOCH3CH3CH2CH2OCH320.CH2Cl+(CH3)3CONaCH2OC(CH3)321.(CH3)2CHCl+NaSH(CH3)2CHSH522.BrCH2BrNaOHBrCH2OH23.ClCH2CHCH2ClNaOHHOCH2CHCH2Cl24.CH3CH2CHCH2C6H5OHH2SO4CH3CH2CHCHC6H525.CH2CH2OH+SOCl2CH2CH2Cl26.OH+SOCl2Cl+SO2+HCl27.重排CH3CHCHCH3CH3+CH3CH2CCH3CH3+28.重排CH3C+CH3CH3CH2CH3C+CH3CH2CH329.CH3OCH3+HICH3OH+CH3I30.+HClC6H5CHCH2OCHCl3C6H5CHCH2ClOH31.+HOCH3CH3ONaOCH3CH3CH3CH3CCH3OHCHOCH3CH332.CH3CH2CHO稀NaOH低温CH3CH2CHCHCHOOHCH333.O+CH3CH2MgBr(1)无水乙醚(2)H2O/H+HOCH2CH334.H3O+CH3CCH3O+CH3...
