汪小兰有机化学第四版1017章答案VIP专享

1 第十章：羧酸及其衍生物 10.1 用系统命名法命名（如有俗名请注出）或写出结构式 答案：a. 2－甲基丙酸 2－Methylpropanoic acid (异丁酸 Isobutanoic acid ) b. 邻羟基苯甲酸（水杨酸）o－Hydroxybenzoic acid c. 2－丁烯酸 2－Butenoic acid d 3－溴丁酸 3－Bromobutanoic acid e. 丁酰氯 Butanoyl Chloride f. 丁酸酐 Butanoic anhydride g. 丙酸乙酯 Ethyl propanoate h. 乙酸丙酯 Propyl acetate i. 苯甲酰胺 Benzamide j. 顺丁烯二酸 Maleic acid s.COt.H3CCOk.COOCH3COOCH3l.HCOOCH(CH3)2m.CH3CH2CONHCH3 10.2 答案：酸性排序 g > a > b > c > f > e > h > d 10.3 写出下列反应的主要产物 a.Na2Cr2O7--H2SO4COOHCOOH+COOHCOOHb.(CH3)2CHOH+COOCH(CH3)2H3CCOClH3Cc.HOCH2CH2COOHLiAlH4HOCH2CH2CH2OHd.NCCH2CH2CN+H2ONaOH－ OOCCH2CH2COO－H+HOOCCH2CH2COOHe.CH2COOHCH2COOHBa(OH)2Of.CH3COCl+CH3无水 AlCl3CH3COCH3+CH3COCH3g.(CH3CO)2O+OHOCOCH3h.CH3CH2COOC2H5NaOC2H5CH3CH2COCHCOOC2H5CH3 i.CH3COOC2H5+CH3CH2CH2OHH+CH3COOCH2CH2CH3+C2H5OHj.CH3CH(COOH)2CH3CH2COOHk.COOH+HClClCOOH+ CO2 2 l.2+HOCH2CH2OHH+COOCH2CH2OOCm.COOHLiAlH4CH2OHCOOHn.HCOOH+OHHCOOH+o.CH2CH2COOC2H5CH2CH2COOC2H5NaOC2H5OCOOC2H5p.NCONH2OH－－NCOO+NH3q.CH2(COOC2H5)2+H2NCONH2HNNHOOO 10.4 用简单化学方法鉴别下列各组化合物： 答案： a. KmnO4 b. FeCl3 c. Br2 or KmnO4 d. ①FeCl3 ②2,4-二硝基苯肼或 I2 / NaOH 10.5 完成下列转化： a.OCNOHH+COOHOHb.CH3CH2CH2BrCN－CH3CH2CH2CNH+CH3CH2CH2COOHc.(CH3)2CHOHCrO3.(Py )2(CH3)2C O(CH3)2CCNOHH+(CH3)2CCOOHOHd.CH3CH3KMnO4COOHCOOHCOOHCOOHBa(OH)2OOOOOOe.(CH3)2C=CH2HBr(CH3)3CBrMgEt2O(CH3)3CMgBrCO2H+ / H2O(CH3)3CCOOHf.CH3BrAlCl3CH3KMnO4COOHBr2FeCOOHBrg.HCCHH2OH+Hg2+,CH3CHOKMnO4CH3COOHCH3CH2OHH+CH3COOC2H5HCNH2OHCN1)2)H2OH2O 3 h.OHNO3HOOC(CH2)4COOHOi.CH3CH2COOHLiAlH4CH3CH2CH2OHHBrCH3CH2CH2BrMgEt2OCH3CH2CH2MgBrOH+CH3CH2CH2CH2CH2OHKMnO4CH3CH2CH2CH2COOH或CH3COCH2COOC2H5EtONaCH3CH2CH2BrCH3 CO CHCH2CH2CH3COOC2H5浓OH－CH3(CH2)3COOHj.CH3COOHCl2PCH2COOHClCN－CH2COOHCNEtOHH+ ,CH2(COOC2H5)2k.OOONH3CH2COONH4CH2CONH2l.CO2CH3OHH+H2OCOOHOH(CH3CO)2OCOOHOOCCH3m.CH3...